FePcBN-16-6

Date

17.03.2023

Synthesis

  1. Preheat Fisherbrand FB15049 ultrasonic bath filled with ethyleneglycol to 80°C
  2. Add 100.3 mg of h-BN, 20.3 mg of FePcCl and 200 ml of DMF to 250 ml 2-neck round-bottom flask
  3. Close wide neck with stopper and purge flask with Ar for 10 min through small neck
  4. Close small neck with stopper
  5. Place flask to US-bath and keep for 4 hr
  6. Leave flask overnight in a room with air conditioner set to 22°C
  7. Separate solid particles from DMF using Hetich Universal 320 centrifuge at 6000 rpm for 60 min
  8. Wash with distilled water twice using ultrasonic treatment with US Bandelin Sonopuls UW 2200 at 50% power for 1 min and centrifugation at 6000 rpm for 60 min
  9. Make 80 ml of suspension and add it to 250 ml polypropylene flask
  10. Freeze suspension with liquid nitrogen
  11. Dry in Cryst alpha 1-2 LO plus freeze-dryer at 0.05 mbar

ms = 49.7 mg

Sample after holding in air-conditioned room overnight Sample after washing Sample after drying